Organotin compounds in the environment an overview of the book

It is also a summary of the environmental effects of organotin compounds on nontarget organisms, ranging from oyster shell thickening and growth anomalies to imposex in the common dogwhelk nucella. An introduction to organotin compounds and their use in antifouling coatings. The need for research on environmental effects will grow concomitant with. Download citation organotin compounds in the environment an overview tin.

Organotin compounds have demonstrated significant economic benefits, as well as environmental costs, as a result of their varied industrial and agricultural uses and applications. The impact of organotin compounds in the environment is assessed, based on a critical survey of the published literature. This has given rise to an increase of the worldwide production of organotin compounds during the last 50 years. Organotin compounds in the environment organometallic. Organotin compounds in the environment an overview. A proposal for health and environmental hazard classification of dioctyl and dibutyl tin compounds is under discussion within the eu. The commercial production of organotin compounds by using the grignard reagent nr mgcl fig. Emma popek, in sampling and analysis of environmental chemical pollutants second edition, 2018. Abstractdue to the extensive use of organotin compounds otcs in.

Tin has a larger number of its organometallic derivatives in commercial use than any other element. This book provides an overview of the induction mechanism of imposex caused by organotin compounds in gastropods, as well as fundamental information on the physiology and biochemistry of reproduction in mollusks. The emphasis of this chapter and this book is on tributyltin tbt, the principal biocidal ingredient of most organotin antifouling paints. For more than 50 years, organotin compounds have been used in almost all sectors of industry. Overview of decay rates of tbt and other organotins in water and sediments. Review organotin compounds in the environment an overview.

High amounts of the toxic tributyltin and some other organotin derivatives can be found not only in water and sediments, but also various aquatic organisms and. Organotin compound an overview sciencedirect topics. It is also a summary of the environmental effects of organotin compounds on. Pdf organotin compounds in the environment an overview. Pdf organotin compounds and environment researchgate. Pdf history on organotin compounds, from snails to humans. Organotin compounds are also utilized commercially in polymers in film for food. The process gives high yields but the use of high amounts of solvents is required.

The high toxicity of trisubstituted derivatives towards aquatic organisms has resulted in. As a consequence, specific parts of the environment are affected by the emission of these xenobiotics. If n3, the compound has the highest toxicity, for example etesnoac has ld so 4mgkg rats and this is the most toxic compound. An introduction to organotin compounds and their use in.

After a brief introduction, the properties and characteristics of organotin compounds are outlined, with notes on methods of manufacture, patterns of use and chemical properties. Due to the wide industrial applications considerable amounts of the organotins have entered various ecosystems. Organotin compounds affect natural killer nk on lymphocytes in human. Organotins are organometallic compounds based on organic derivatives of the tetravalent tin, such as methyl, butyl, octyl, phenyl organotins, and others. The emphasis of this chapter and this book is on tributyltin tbt, the principal. Methods for the analysis of organotin speciation in the environment. History on organotin compounds, from snails to humans. This has given rise to an increase of the worldwide production of organotin compounds during the. While sn in its inorganic form is considered to be nontoxic, the toxicological pattern of the organotin compounds is complex. It is the more valuable because research on tbt has often been published in less accessible journals and symposium proceedings. A useful resource for all researchers and scientists in industry working with organometallic compounds, including, chemists, environmentalists and ecologists. Pdf organotin compounds in the environment francesca. Organometallic compounds in the environment wiley online. It will help to minimize the duplication of research and speed the introduction of legislation around the world to control organotin pollution.